赣南崇义淘锡坑钨矿床氢、氧、硫同位素地球化学研究   总被引：11，自引：2，他引：9  

宋生琼  胡瑞忠  毕献武  魏文凤  石少华 《矿床地质》2011,30(1):1-10

赣南崇义县淘锡坑钨矿位于南岭东西向构造带东段与武夷山NE-NNE向构造带南段的复合部位,属于以石英脉型黑钨矿为主的钨多金属矿床.文章通过氧、氧、硫同位素地球化学特征的研究,探讨了淘锡坑钨矿成矿流体的来源及演化.研究结果显示:δD值介于-77‰～-45‰之间;石英矿物的δ18O值介于+7.3‰～+12.2‰之间,计算给出...  相似文献   

Variation of mineral composition,fabric and oxygen fugacity from massive to foliated eclogites during exhumation of subducted ocean crust in the North Qilian suture zone,NW China   总被引：2，自引：0，他引：2  

Y. CAO  S. G. SONG  Y. L. NIU  H. JUNG  Z. M. JIN 《Journal of Metamorphic Geology》2011,29(7):699-720

Eclogites from the North Qilian suture zone are high‐pressure low‐temperature metamorphic rocks of ocean crust protolith, and occur in both massive and foliated varieties as individual blocks of tens to hundreds of metres in size. The massive type is weakly deformed and shows granoblastic texture characterized by a coarse‐grained peak mineral assemblage of Grt¹ + Omp¹ + Ph + Rt ± Lws (or retrograde Cz). In contrast, the foliated type is strongly deformed and shows a fine‐grained retrograde mineral assemblage of Grt² + Omp² + Cz + Gln + Ph. Both total FeO and aegirine contents in omphacite, as well as X_Fe[=Fe³⁺/(Fe³⁺ + Al^VI)] in clinozoisite/epidote, increase significantly from massive to foliated eclogites. Lattice preferred orientation (LPO) of omphacite, determined by electron back‐scatter diffraction analysis, is characterized by weak and strong SL‐type fabrics for massive and foliated eclogites, respectively. Clinozoisite/epidote also developed SL‐type fabric, but different from the LPOs of omphacite in <010> and <001> axes, owing to their opposite crystallographic long and short axis definitions. The transition of deformation mechanism from dislocation creep to diffusive mass transfer (DMT) creep in omphacite and the concomitant retrograde metamorphism both are efficiently facilitated when the original coarse‐grained Omp¹ + Grt¹ + Lws assemblage is dynamically recrystallized and retrogressed into the fine‐grained Fe³⁺‐rich assemblage of Omp² + Grt² + Cz + Gln. The DMT process with concomitant anisotropic growth assisted by fluids is considered to be an important deformation mechanism for most minerals in the foliated eclogite. P–T estimates yielded 2.3–2.6 GPa and 485?510 °C for the massive eclogite and 1.8–2.2 GPa and 450?480 °C for the foliated eclogite. The significant increase in total Fe and Fe³⁺ contents in omphacite and clinozoisite/epidote from massive to foliated eclogite suggests changes in mineral compositions accompanied by an increase in oxygen fugacity during ductile deformation associated with exhumation. The LPO transition of omphacite, clinozoisite and rutile from weak SL‐type in massive eclogites to strong SL‐type in foliated eclogites is interpreted to represent the increment of shear strain during exhumation along the ‘subduction channel’.  相似文献   

碳还原法分析硫酸盐的氧同位素组成   总被引：1，自引：0，他引：1  

万德芳  李延河  秦燕 《矿床地质》2011,30(4):749-753

硫酸盐矿物是自然界最常见矿物,也是自然界少数具有氧同位素非质量分馏效应的矿物之一.硫酸盐矿物的氧同位素组成可以为研究其形成过程和生成条件提供大量信息.目前,在国内外分析硫酸盐氧同位素的3种方法中,碳还原方法乃是分析硫酸盐中氧同位素组成的最精准方法.本次研究建立了分析硫酸盐中氧同位素组成的碳还原方法,介绍了硫酸钡的分析流...  相似文献   

西藏谢通门县邦弄含铁电英岩脉的地质特征及成因分析   总被引：1，自引：0，他引：1  

夏祥标  郑来林  李军敏  李再会 《矿床地质》2011,30(4):742-748

文章介绍了西藏谢通门县邦弄地区含铁电英岩脉的地质特征.电英岩脉的延伸方向大致与区内的断层平行,围岩为中粒斑状角闪黑云二长花岗岩.电英岩脉中见有不同程度的铁矿化,共有23条矿化较好的含铁电英岩脉.含铁电英岩脉中矿石矿物为赤铁矿(镜铁矿),脉石矿物为石英、电气石及少量的白云母和长石.矿石具叶片状、鳞片状结构,块状构造,矿石...  相似文献   

Mixing of magmatic CO₂ into volcano groundwater flow at Aso volcano assessed combining carbon and water stable isotopes     

Makoto Yamada  Shinji Ohsawa  Kohei Kazahaya  Masaya Yasuhara  Hiroshi Takahashi  Kazuhiro Amita  Hideo Mawatari  Shin Yoshikawa 《Journal of Geochemical Exploration》2011

To understand deep groundwater flow systems and their interaction with CO₂ emanated from magma at depth in a volcanic edifice, deep groundwater samples were collected from hot spring wells in the Aso volcanic area for hydrogen, oxygen and carbon isotope analyses and measurements of the stable carbon isotope ratios and concentrations of dissolved inorganic carbon (DIC). Relations between the stable carbon isotope ratio (δ¹³C_DIC) and DIC concentrations of the sampled waters show that magma-derived CO₂ mixed into the deep groundwater. Furthermore, groundwaters of deeper areas, except samples from fumarolic areas, show higher δ¹³C_DIC values. The waters' stable hydrogen and oxygen isotope ratios (δD and δ¹⁸O) reflect the meteoric-water origin of that region's deep groundwater. A negative correlation was found between the altitude of the well bottom and the altitude of groundwater recharge as calculated using the equation of the recharge-water line and δD value. This applies especially in the Aso-dani area, where deeper groundwater correlates with higher recharge. Groundwater recharged at high altitude has higher δ¹³C_DIC of than groundwater recharged at low altitude, strongly suggesting that magmatic CO₂ is present to a much greater degree in deeper groundwater. These results indicate that magmatic CO₂ mixes into deeper groundwater flowing nearer the magma conduit or chamber.  相似文献   

福建云霄晶洞花岗岩及含石榴子石伟晶岩的硅氧同位素研究   总被引：1，自引：0，他引：1  

高建飞  丁悌平 《地质论评》2011,57(5):670-674

在运用常规方法和激光烧蚀同位素分析方法分别对云霄晶洞花岗岩和伟晶岩(长石、石英和石榴子石)的硅、氧同位素组成进行研究的基础上,探讨了晶涧花岗岩及其含石榴子石伟晶岩的物质来源及形成条件.伟晶岩中的石英和长石的氧、硅同位素组成分别较之花岗岩中的石英和长石的氧、硅同位素组成,均未发生明显变化,表明二者岩浆来源一致.云霄县的乌...  相似文献   

广东凡口铅锌矿碳、氧同位素地球化学特征及其地质意义   总被引：3，自引：0，他引：3  

韩英 《地质与勘探》2011,47(4):642-648

广东凡口超大型铅锌矿床产于泥盆系台地碳酸盐岩中,矿床成因仍存在较大争议。通过含矿地层岩石以及矿石系统的碳、氧同位素分析研究,发现紫色砂岩的褪色蚀变和碳酸盐岩的白云石化与盆地卤水作用密切相关,褪色蚀变砂岩中的碳酸盐胶结物具有显著低的δ^13C和δ^18O值,与矿石中碳酸盐矿物相似,白云石化的碳酸盐岩之δ^13c和δ^18...  相似文献   

塔里木盆地西北缘海相白垩系-古近系界线沉积物环境指标研究   总被引：1，自引：1，他引：0  

孟昌  孟庆泉  杜芳芳  杨进云  张曼  吴小斌  魏引杰  宋春晖 《沉积学报》2011,29(2):245-254

发生于中生代-新生代之间的事件是地质历史上一次重大灾变和异常事件,因此白垩系-古近系之间的界线(K/T界线)就成为全球最重要的地质界线之一.通过对塔里木盆地西北缘乌恰地区库孜贡苏河剖面海相上白垩统-古新统地层的岩性和沉积环境变化以及地球化学特征研究,重点利用沉积物色度、有机碳含量、碳酸钙和碳、氧稳定同位素的明显异常变化...  相似文献   

黔南宾夕法尼亚亚纪珊瑚礁相腕足动物氧同位素组成及其古水温信息     

杨丽丽  巩恩普  张永利  关长庆  孙宝亮  常洪伦 《沉积学报》2011,29(3):458-464

黔南宾夕法尼亚亚纪Triticites带内大型Fomitchevella珊瑚礁群落中见附礁生长的腕足动物Striatifera striata 和Enteletoides shuichengensis,XRD测试结果显示Striatifera striata壳体次生层为保存较好、成分纯净的低镁方解石,完全未受到成岩作用...  相似文献   

青藏高原东南缘哀牢山大坪金矿成矿流体演化   总被引：5，自引：2，他引：3  

朱路华  戚学祥  彭松柏  李志群 《岩石学报》2011,27(11):3395-3408

大坪金矿是青藏高原东南缘哀牢山构造带中的大型石英脉型金矿床,由北矿区和南矿区组成.北矿区和南矿区的成矿流体包裹体均一温度及其氢、氧、硫同位素、气液相成份的测试结果表明其成矿温度为:187～329℃(平均为281℃)和168～338℃(平均为264℃)、氢同位素组成(δDV-SMOW)为:-70‰～-81‰和-71‰～-86‰、氧同位素组成(δ18OH2o)为:2.9‰～9.8‰和3.5‰～5.1‰、硫同位素值(δ34S)为:0.7‰～15.5‰和10.6‰～15.8‰.在氢-氧同位素图解上,所有样品均落在岩浆水和地下水趋势线之间.其中,北矿区样品更靠近岩浆水区域,部分样品落在岩浆水区域内,南矿区相时靠近地下水区域.流体包裹体成份分析表明,气相成份主要为H2O和CO2,其次为N2,并含有少量CH4、C2H2、C2H4、C2H6和CO;离子成份主要为K+、Na+、Ca2+、Cl-和SO42-,及少量NO3-、Mg2+、F-和Br-.含金石英脉ESR定年数据揭示了北矿区成矿时代为27.2～29.1Ma,南矿区为17.3～22.1Ma.总体来看,北矿区成矿时代要早于南矿区;北矿区成矿流体是以岩浆流体为主,并有少量地下水混入,而南矿区成矿流体中地下水的参与程度要大于北矿区;成矿流体具有从北矿区向南矿区、从早到晚以及从深部向浅部,岩浆流体组分相对减少,地下水组分逐渐增加的演化趋势.  相似文献